IIT JEE Chemistry - Study Guide - 4. Chemical Thermodynamics (XII Portion)

Sections in the chapter (Jauhar’s Book CBSE)

4.1 Some basic terms and concepts
4.2 Internal energy, heat and work
4.3 First law of thermodynamics
Practice Problems 4.1 to 4.6
4.4 Enthalpy and Enthalpy change
P.P 4.7 to 4.10
4.5 Limitations of first law of thermodynamics: Need of second law
4.6 Randomness and spontaneity
4.7 Entropy
4.8 Second law of thermodynamics
4.9 Entropy change during phase transition
P.P. 4.11 to 4.17
4.10 Gibbs Free energy and free energy change
4.11 Free energy change for predicting feasibility of a reaction
P.P. 4.18 to 4.23
4.12 Standard free energy change
4.13 Standard free energy change and equilibrium constant
P.P. 4.24 to 4.31
4.14 Gibbs free energy change and nonmechanical work
4.15 Absolute entropies and third law of thermodynamics
P.P 4.35 to 4.36


Additional numerical problems for practice 1 to 10
Conceptual Questions with Answers: 12

Revision Exercises
Very Short Answer questions 25
Short Answer Questions 48
Long Answer Questions 10

Competition File
Numerical problems for competitive examinations 17
Objective Questions: 36
Fill in the blanks: 10
True or False: 10


Study Plan

Day 1

4.1 Some basic terms and concepts
4.2 Internal energy, heat and work
4.3 First law of thermodynamics

Day 2

Practice Problems 4.1 to 4.6
4.4 Enthalpy and Enthalpy change
P.P 4.7 to 4.10

Day 3
4.5 Limitations of first law of thermodynamics: Need of second law
4.6 Randomness and spontaneity
4.7 Entropy
4.8 Second law of thermodynamics
4.9 Entropy change during phase transition

Day 4
P.P. 4.11 to 4.17
4.10 Gibbs Free energy and free energy change
4.11 Free energy change for predicting feasibility of a reaction

Day 5
P.P. 4.18 to 4.23
4.12 Standard free energy change
4.13 Standard free energy change and equilibrium constant
P.P. 4.24 to 4.31

Day 6

4.14 Gibbs free energy change and nonmechanical work
4.15 Absolute entropies and third law of thermodynamics
P.P 4.35 to 4.36

Day 7

Additional numerical problems for practice 1 to 10
Conceptual Questions with Answers: 12


Day 8
Revision Exercises: Very Short Answer questions 25

Day 9
Revision Exercises: Short Answer Questions 1 t o 24
Day 10
Revision Exercises: Short Answer Questions 25 to 48

Day 11
Competition File: Numerical problems for competitive examinations 17

Day 12

Competition File: Objective Questions: 1 to 18

Day 13
Competition File: Objective Questions: 19to 36

Day 14

Competition File: Fill in the blanks: 10
Competition File: True or False: 10

Day 15
Concept Revision
Fromula Revision

Day 16 to 30

Revision of the chapter/Extra problems from other books like R.C. Mukherjee, Test Paper books etc..
Use all available time productively to improve your understanding, ability to solve problems and recollection of principles.


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Updated 3 Feb 2016, 11 March 2009